This innovative protective coating prevents dendrite growth and undesirable side reactions, making zinc-ion batteries more stable and practical

DAEJEON, South Korea, Aug. 13, 2025 /PRNewswire/ -- Seeking to improve zinc-ion batteries as a safe and affordable alternative to lithium-ion batteries, researchers have developed a new zinc-bonded polyacrylic acid (ZHP) layer that prevents dendritic growth and stabilizes the anode. The resulting ZHP-coated zinc anode demonstrates excellent cycling performance and stability, supporting the development of next-generation ZIBs with enhanced stability.

Aqueous zinc-ion batteries (ZIBs) are gaining attention as a safer and more affordable alternative to lithium-ion batteries. Unfortunately, zinc anodes in ZIBs suffer from undesirable side reactions and sharp dendrite formation during charging and discharging, which impacts their cycling performance and stability. Previous attempts to use protective coatings were often too thick or difficult to manufacture, limiting their real-world use.

In a breakthrough, a research team led by Associate Professor Woo-Jin Song from the Department of Organic Materials Engineering at Chungnam National University, South Korea, designed a new ultra-thin selective-ion transport layers (SITL) that is both effective and easy to produce. "In this study, we developed a nanoscale zinc-bonded polyacrylic acid (Zn–PAA) protective layer for zinc anodes via oxygen plasma treatment," explains Dr. Song. "Unlike conventional thick and complex coatings, our approach offers a simpler fabrication process and is scalable for large-area applications." Their study was made available online on May 8, 2025, and published in Volume 515 of the Chemical Engineering Journal on July 1, 2025.

This new SITL is based on polyacrylic acid (PAA), which can prevent direct contact between the zinc anode and water-based electrolyte, inhibiting corrosion. This significantly reduces dendritic growth, stabilizing the anode interface. Thanks to its hydrophilicity, it also improves ion transfer between the electrolytes and the anode, promoting uniform distribution of zinc-ions and enhancing battery performance.

However, bare PAA tends to dissolve in water-based electrolytes, reducing cycling performance. To prevent this, the researchers applied oxygen plasma treatment to zinc-anode, which enhanced adhesion between PAA the layer and the anode surface. The PAA was deposited on the treated zinc-anode using the cost-effective and scalable spin-coating technique, resulting in a nanoscale PAA coating. The PAA-coated anode was then heated on a hot plate, forming the zinc-bonded PAA (ZHP) layer.

The ZHP coated zinc anode demonstrated remarkable performance. In full cells, it retained 95% of its capacity after 500 cycles. In pouch cells, the anode demonstrated stable cycling for over 300 cycles.

"The enhanced stability of water-based electrolytes makes ZHP based ZIBs ideal for safety-critical industries such as grid-scale energy-storage systems and detection sensors." remarks Dr. Song. "And due to their low cost and toxicity, these batteries are also well-suited for portable electronics and wearables."

Reference

About the institute
Chungnam National University (CNU), founded in 1952 in Daejeon, South Korea, is a leading national university with a strong focus on research and education. Thanks to its location near the Daedeok Innopolis R&D hub, it excels in fields such as biotechnology, materials science, and information technology.

About Associate Professor Woo-Jin Song 
Dr. Woo-Jin Song is an Associate Professor at Chungnam National University, where his research focuses on developing next-generation batteries. He specializes in polymer synthesis and analysis and the design of polymers for metal interface reactions. He received his PhD from UNIST in 2018 and completed postdoctoral training at Stanford University.

Contact:
Gaeun Kim
Chungnam National University
+82 42-821-6239
399589@email4pr.com
https://plus.cnu.ac.kr/html/en/ 

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SOURCE Chungnam National University